Pressurized water stress corrosion cracking

Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Evaluation of primary water stress corrosion cracking. Primary water stress corrosion cracking pwscc is an intergranular cracking. The nozzles were made of forged and annealed alloy 600 uns n06600 base material containing welds with alloys 82 uns n06082 and 182 uns w86182. Nuclear reactors nickel alloys primary water stress corrosion cracking. Stress corrosion cracking international institute of. However, with the discovery of stress corrosion cracking denoted as primary water stress corrosion cracking pwscc at several pwr plants over the past 5 years, the first being at v. Affecting stress corrosion cracking in stainless steel piping in pressurized water reactors addressees all holders of an operating license or construction permit for a nuclear power pressurized water reactor pwr issued under title 10 of the code of federal regulations 10 cfr part 50. The crack growth rate cgr increased with increasing do content in the simulated pwr primary water. Within the pressure vessels, there are many internal structures that support the reactor core,maintain fuel assembly alignment, etc. Uniform corrosion, flowaccelerated corrosion fac, pitting, stress corrosion cracking scc, environmentally assisted fatigue and hydrogen embrittlement can all affect the major components of pwrs, despite. The corrosion fatigue cf and stress corrosion cracking scc crack growth rates cgrs of type 316ln ss and its welds that are used for pressurized water reactor primary water components were.

The purpose of this research was to compare the stress corrosion cracking scc resistance of materials used at the present time for steam generator sg tubing in pressurized water reactor pwr. This alloy is wellknown to be susceptible to stress corrosion cracking. Primary water stress corrosion cracking of highchromium, nickelbase welds near dissimilar metal weld interfaces nuregcr7226 on this page. Affecting stress corrosion cracking in stainless steel piping in pressurized water reactors addressees all holders of an operating license or construction permit for a nuclear power pressurized water reactor pwr issued under title 10 of the. Primary water stress corrosion cracking pwscc of inconel 600 united states nuclear regulatory commission office of nuclear reactor regulation washington, d. Stress corrosion cracking behavior of alloy 182 weld in.

Assessment of weld overlays for mitigating primary water. It is especially important to avoid any mechanical tensile stress concentration, which will occur at sharp edges and notches. Strainhardening may play an important role in the occurrence of intergranular scc. A highresolution characterization of the initiation of. Of these, 69 are pressurized water reactors pwrs and 35 are boiling water.

The work in this article is part of a project to develop a quantitative description of stress corrosion cracking scc on the secondary side of pressurized water reactor pwr steam generator tubing based on existing information from operating plants and from laboratory experiments. Nrc staff actions to address primary water stress corrosion cracking in dissimilar metal butt welds the industry actions to develop and implement the mrp9 inspections allowed the nrc staff to pursue a process to codify requirements involving all stakeholders rather than to initiate other regulatory actions. The description above for scc behavior in coldrolled austenitic steels in simulated pwr primary water is a similar scenario to that for the mechanism of primary water stress corrosion cracking of alloy 600 in simulated pwr primary water. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Corrosion in pressurized water reactors pwrs sciencedirect. Alloy 600, a nicrfe alloy, is widely used as the pressure boundary component of pressurized water reactors pwrs, such as steam generator. Outside diameter stress corrosion cracking of stainless. Abstract the influence of dissolved hydrogen on primary water stress corrosion cracking pwscc of mill annealed alloy 600 was studied at temperatures ranging from 320 to 36012 and hydrogen contents ranging from 0 to 4 ppm using the slow strain rat. Influence of dissolved hydrogen on primary water stress. Alloys 52 and 152 are highchromium weld metals used in reactor pressure vessel head penetration nozzles and as overlays, inlays, or onlays for dissimilar metal piping welds. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Stress corrosion crack scc initiation of three millannealed alloy 600 heats. The nuclear industry has developed several methods for mitigation of pwscc to prevent costly repairs to pressurized water reactor pwr components including surface stress improvement by peening.

Stress corrosion cracking of alloy 600 in pwr primary water. Evaluation of laser peening for mitigation of primary. Effects of marine environments on stress corrosion. However, the inspections required by order ea03009 will ensure that cracking is identified in. Cracking can initiate at the inside surface of these materials, in part, because of tensile residual stresses introduced by welding. In many cases, problems with stress corrosion cracking scc can. Quantitative assessment of submodes of stress corrosion. Evaluation of primary water stress corrosion cracking growth rates.

Iaea nuclear energy series stress corrosion cracking in light. Intergranular stress corrosion cracking in pressurized water reactor safety injection accumulator nozzles united states nuclear regulatory commission office of nuclear reactor regulation washington, d. Stress corrosion crack initiation of alloy 690 in simulated pressurized water reactor primary water was studied through highresolution characterization of grain boundaries at different stages of the initiation process. Effect of dissolved oxygen content on stress corrosion. Stress corrosion cracking scc is a significant material degradation for major components of both pressurized water reactors pwrs and boiling water reactors. Stress corrosion cracking tests were conducted in 36oc 680of pressurized water reactor pwr primary water using aerospacegrade super 718 with heat treatment variations which altered the local grain boundary chemistry. Current nrc perspectives concerning primary water stress. Accelerated testing of stress corrosion crack initiation and growth of alloy 600 and alloy 690 in pressurized water reactor pwr is routinely conducted to reduce the time of the experiment on. Stress corrosion cracking of austenitic stainless steels 1011820 technical update, september 2005. A reactor pressure vessel rpv in a nuclear power plant is the pressure vessel containing the nuclear reactor coolant, core shroud, and the reactor core.

Chloride stress corrosion cracking in austenitic stainless. Primary water stress corrosion cracking of highchromium. The earliest incidents of irradiation assisted stress corrosion cracking iascc in bwrs occurred during the early 1960s and were associated with cracking of type 304 stainless steel fuel cladding, where the driving forces for cracking were the increasing tensile hoop stress in the cladding due to the swelling fuel and the highly oxidizing conditions in the water. Pdf evaluation of primary water stress corrosion cracking. Effect of surface treatments on microstructure and stress.

Primary water stress corrosion cracking pwscc of inconel 600 addressees. Although the nickel base materials were different from the present study, there are similarities to. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Several major disasters have involved stress corrosion cracking, including the rupture of high pressure gas transmission pipes, the explosion of boilers, and the destruction of power. All holders of operating licenses or construction permits for pressurized. Summer in south carolina, the issue has become significant for the us pwr industry.

While stress corrosion cracking scc is a major service life limiting mechanism for both pressurized water reactors pwrs and boiling water reactors bwrs, most of the corrosion research. For alloy 600, primary water stress corrosion cracking pwscc is one of the key material degradation mechanisms in pressurized water reactors pwrs. Because pwscc was not properly considered in vintage pressurized water. Effects of chloride and oxygen on stress corrosion. The primary purpose of this research is to examine the stress corrosion cracking scc resistance of alloy 800ng in pressurized water reactor pwr primary water and pressurized heavy water reactor phwr primary water. Steam purity stress corrosion cracking, gek7 2281 general description remain dissolved in the steam and pass into the turbine. A method to assess and predict pressurized water stress corrosion cracking in operational nuclear power plants and the effect of adding zinc compounds into. For these systems, the utilities have always controlled boiler water water purity input to the boiler is a good. Stress corrosion crack initiation of alloy 600 in pwr primary water. Stress corrosion cracking growth of alloy 800ng in. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes.

Stress corrosion crack growth tests of a cold worked nuclear grade 316l stainless steel were conducted in simulated pressurized water reactor pwr primary water environment containing various dissolved oxygen do contents but no dissolved hydrogen. Primary water stress corrosion cracking analysis in alloy. A large variety of the structural metals present in primary and secondary circuits of pressurized water reactors pwrs suffer corrosion. Stress corrosion cracking scc is a significant ageing degradation mechanism for major components of both pressurized water reactors pwrs and boiling. Abstract the aging of water cooled and moderated nuclear steam supply systems inevitably has given rise to many material corrosion problems of which stress corrosion cracking scc is one of the mo. The nozzles were made of forged and annealed alloy 600 uns n06600 base material containing welds with. Stress corrosion cracking facts and how to reduce the. Stress corrosion cracking scc is a significant ageing degradation mechanism for major components of both pressurized water reactors pwrs and boiling water reactors bwrs. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Stress corrosion cracking of alloy 718 in pressurized. Pressurized water nuclear reactors in the united states generate about percent of u. Virtanen, stress corrosion cracking initiation and short crack growth behaviour in alloy 182 weld metal under simulated boiling water reactor hydrogen water chemistry conditions, in, 2016.

One of the main failure mechanisms that cause risks to pressurized water reactors pwr is the primary water stress corrosion cracking pwscc occurring in. Though efficient, these reactors face a unique challenge with stress corrosion cracking scc. Effect of surface treatments on microstructure and stress corrosion cracking scc of 308l weld metal in primary pressurized water reactor environment. Stress corrosion cracking is a form of localised failure which is more severe under the combined action of stress and corrosion than would be expected from the sum of the individual effects acting alone. Stress corrosion crack initiation of two thermallytreated, coldworked cw alloy 690 uns n06690 materials was investigated in 360oc simulated pwr primary water using constant load tensile clt tests and blunt notch compact tension bnct tests equipped with direct current potential drop dcpd for insitu detection of cracking. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. All holders of operating licenses or construction permits for pressurized water.

This mechanism is characterized by corrosion in the microscopic granular composition of a metals surface. It was found that a compact layer of cr 2 o 3 initially forms over a migrated grain boundary, driven by the diffusion of cr. This cracking was found first in piping and then became a significant issue for reactor pressure vessel rpv internals and rpv nozzle welds including nickel welds. Many of these nozzles are joined to the rpv by dissimilar metal welds that may be affected by stress corrosion cracking andor corrosion fatigue 2. Stress corrosion cracking an overview sciencedirect topics. For several decades pressurized water reactors have experienced primary water stress corrosion cracking pwscc within alloy 600 components and welds. Intergranular stress corrosion cracking growth behavior of.

This type of corrosion is one of the primary lifelimiting degradation mechanisms of nickelbase alloy pressure boundary components, such as. Pdf for alloy 600, primary water stress corrosion cracking pwscc is one of the key material degradation mechanisms in pressurized water. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Alloy 600 is still in use in existing pressurized water reactor pwr. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.

Originally selected for its high corrosion resistance, it exhibited, after a long operation period, susceptibility to stress corrosion cracking scc in pwr. Stress corrosion crack initiation in machined type 316l. Stress corrosion, also known as stress corrosion cracking, is a type of corrosion that occurs due to the simultaneous action of a corrodent and a sustained tensile stress. Primary water stress corrosion cracking behavior of an. Introduction in the united states currently there are approximately 104 operating light water reactors. Extensive laboratory testing has shown that intergranular stress corrosion cracking igscc requires the presence of the following three key elements. Alloy 600 cracking and boric acid corrosion of lightwater reactor pressure vessel. Shallow intergranular attack andor cracks were found on most highenergy grain boundaries. Primary water stress corrosion cracking pwscc of inconel 600. In recent years, accidents of stress corrosion cracking scc in 316l ss pipes were reported in pwrs. Nrc regulatory issue summary 200825 primary water stress. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Steam generator sg drain nozzles on the cold leg side in a pressurized water reactor pwr have exhibited stress corrosion cracking scc.